CATALYSTS OF REACTIONS INVOLVING HYDROGEN: SYNTHESIS, FEATURES, ACTIVITY (REVIEW)

  • Дмитрий Владимирович Смирнов
  • Дмитрий Алексеевич Прозоров
  • Андрей Владимирович Афинеевский
  • Кирилл Андреевич Никитин
Keywords: adsorption, hydrogen, catalyst, activity, synthesis

Abstract

The paper discusses issues related to catalysts of reactions involving hydrogen. Data on various methods of synthesis of deposited and massive catalysts of similar chemical composition are presented. Some physico-chemical and operational characteristics of catalysts obtained by deposition of an active metal on various substrates are shown. Data on the features of hydrogen adsorption in various states on the catalyst surface are presented. The data obtained were determined by low-temperature adsorption, infrared spectrometry, and calorimetry. The features of determining the activ-ity of catalysts in various reactions involving hydrogen, such as liquid-phase hydrogenation, methanation, methanol synthesis, and hydrotreating, are analyzed. Data on catalytic poisons and their effect on the activity of catalysts are also provided. The data presented in the review make it possible to understand whether the activity of the catalysts correlates with the method of their synthesis.

References

Smirnov D.V., Prozorov D.A., Afineevsky A.V., Osadchaya T.Y. Investigation of hydrogen adsorption on deposited catalysts of reactions involving hydrogen-containing gases. Bulletin of the Technological University. 2021. V. 24. N 6. P. 49-54. (in Russian).

Afineevsky A.V., Knyazev A.V., Lukin M.V., Osadchaya T.Yu., Prozorov D.A., Rumyantsev R.N. Catalytic proper-ties and deactivation of skeletal nickel in liquid-phase hy-drogenation reactions. Kazan: Buk, 2018. 316 p.: ill. – ISBN 978-5-00118-185-9. – Text :direct.

Navalikhina M., Krylov O. Heterogeneous hydrogenation cata-lysts. Russian chemical reviews. 1998. V. 67. N 7. P. 587–616. 4. Kipnis M.A., Gazimzyanov N.R., Aleshin A.I., Agoronov V.S. Pat. 2102145 Russian Federation, IPC B01J37/04 B01J23/755. Method of obtaining a nickel hydrogenation catalyst; applicant and patent holder of JSC NPF Khimtek. N 96117610/04; application no. 05.09.1996; published on 20.01.1998. (in Russian).

Popov Yu.V., Mokhov V.M., Shcherbakova K.V. Synthesis of symmetric and asymmetric dialkylamines during carbonitrile hydrogenation by colloidal catalysis. Proceedings of the Volgo-grad State Technical University. 2015. N 4. P. 38-44.

Batrin Yu.D., Zbarsky V.L., Kozlov A.I., Lukin E.S., Lyubakov P.N., Starovoitov M.K., Tarasov V.A., Tishchenko S.V. Patent 2226187 Russian Federation, IPC C07C205/06 B01J21/04 Method of catalytic liquid-phase nitra-tion of aromatic compounds; applicant and patent holder Kozlov Alexander Ivanovich. N 2002131309/04; application dated 22.11.2002; published on 27.03.2004. (in Russian).

DoludaV.Yu., Demidenko G.N., Sulman M.G. Investiga-tion of the catalytic hydrogenation of nitrobenzene on pal-ladium-containing catalysts in a supercritical carbon dioxide environment. ChemChemTech [Izv. Vyssh.Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2013. V. 56. N 6. P. 62-65.

Anderson J. The structure of metal catalysts. Moscow: Mir Publ., 1978. 485 p. (in Russian).

Vdovina T.N., Bely A.S., Smolikov M.D., Duplyakin V.K. Distribution of the active component over pores of dif-ferent sizes in the structure of oxide carriers. V. Distribution of molybdenum sulfide in the porous structure of γ-Al2O3. Kinetics and catalysis. 1990. Vol. 31. N 4. P. 945-949.

Duplyakin V.K., Bely A.S., Ostrovsky N.M. New data on the state and catalytic properties of platinum in reforming catalysts. Dokl. USSR Academy OF Sciences. 1989. V. 305. N 3. P. 648-652. (in Russian).

Vdovina T.N., Shkuropat S.A. The effect of the conditions of application of the active component on its distribution over the grain and carrier pores in aluminum-molybdenum hydrotreating catalysts. Materials in the collection of the Regional school-seminar of young scientists "Catalysis in oil refining and petrochemistry". Omsk: Interuniversity printing house of OmPI. 1990. P. 62-63. (in Russian).

Shesterkina A.A. Synthesis and investigation of iron–containing catalysts for selective hydrogenation of triple bonds and nitro groups: dis. Candidate of Chemical Sciences: 02.00.15 / Anastasia AlekseevnaShesterkina; scientific director L. M. Kustov; N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences. Moscow, 2018. 140 p.

Alekseenko K.N., Vasilenko A.A., Ivanenko S.S., Karabanov A.V., Kutovoy A.A., Shmanovskaya A.L., YagmurovV.Yu., Sulima S.I. Cobalt Fischer-Tropsch synthesis catalysts deposited on Al2O3 of various polymorphic modifications. Engineering Bulletin of the Don. 2018. N 4.14. Kuzmin A.E., DyatlovaYu.N., Tikhov S.F., Kurkin V.I., Sadykov V.A., Slivinsky E.V., Bogolepova E.I., Tsybulya S.V., Fenelonov V.B., Mordovin V.P., Litvak G.S., Salanov A.N. Fischer-Tropsch synthesis catalysts based on Zr-Fe intermetallides, encapsulated in an Al2O3/Al matrix. Kinetics and catalysis. 2005. Vol. 46. N 5. P. 787-794.

Narochny G.B., Yakovenko R.E., Savostyanov A.P., Bakun V.G. Experience in implementing the technology of a cobalt catalyst for the synthesis of hydrocarbons from CO and H2. Catalysis in industry. 2016. N 1. P. 37-42.

Evgrazieva G.E., Turgumbayeva R.H., Telbaeva M.M., Rosiev A.A., Sakhieva K.M., Dosumov K. Single-component catalysts for the synthesis of a mixture of H2 and CO from natural gas. Gorenje and Plasmochemistry. 2020. V. 18. N 2. P. 81-86. (in Russian).

Hou Z., Bearden R.J., Ferrughelli T.D., Sabato M., Gorbaty M.L., Soled S.L. Pat U.S. 6620313, ICl C10 G45/60 Slurry hydroprocessing using bulk multimetallic catalysts; assignee ExxonMobil Research and Engineering Company. - N 09/869, 983; filled 14.01.2000, applied 30.03. 2004.

Demmin R.A., Riley K.L., Soled S.L, Sabato M.Pat Eu-rope 1171547B1, ICl C10C1/18 C10G65/02 Hydroco- nversion process using bulk group VIII/Group VIB cata-lysts; assignee ExxonMobil Research and Engineering Company. N PCT/US2000/001009; filled 14.01.2000, ap-plied 21.04.2010 bul. 16.

Riley K.L., Klein D.P., Hou Z., Soled S.L., Kerby M.C., McVicker G.B., Ellis E.S., Touvelle M.S., Sabato M. Pat U.S. 6783663, ICl C10G 45/04 Hydrotreating using bulk multimetallic catalysts; assignee ExxonMobil Research and Engineering Company. N 09/869,988; filled 14.01.2000, applied 31.08.2004.

Prozorov D.A., Afineevsky A.V., Smirnov N.N., Sukha- chevYa.P., Chelysheva M.D. Studying the adsorption properties of skeletal nickel in relation to reactive hydrogen using a complex of synchronous thermal analysis and mass spectrometry. Russian Chemical Journal. 2017. V. 61. N 2. P. 39-45. (in Russian).

Knyazheva O.A., Baklanova O.N., Lavrenov A.V., Bulu- chevsky E.A., Drozdov V.A., Trenikhin M.V., Leontieva N.N., Vasilevich A.V., Likholobov V.A. Mechanochemical synthesis of nanocrystalline nickel-molybdenum com-pounds, their morphological features and application in ca-talysis. III. Catalytic properties of massive Ni–Mo sulfide catalysts synthesized by mechanochemical activation. Ki-netics and catalysis. 2014. Vol. 55. N 1. P. 135-143.

Knyazheva O.A., Baklanova O.N., Lavrenov A.V., Bulu chevsky E.A., Gulyaeva T.I., Leontieva N.N., Drozdov V.A., Likholobov V.A., Vasilevich A.V. Mechanochemical synthesis of β-NiMoO4 as a precursor of a massive highly dispersed catalyst for hydrogenation processes of oil frac-tions processing. Catalysis in industry. 2012. N 3. P. 30-37.

Popova N.M., Babenkova L.V., Savelyeva G.A. Adsorp-tion and interaction of the simplest gases with metals of group VIII. Alma Ata: Nauka Publ., 1979. 280 p.

Lukin M.V., Afineevsky A.V. Influence of the concentra-tion of adsorption nanocomplexes on the catalytic activity of skeletal nickel in the reactions of liquid-phase hydro-genation of sodium maleate in aqueous organic media. Physicochemistry of the surface and protection of materials. 2013. V. 49. P. 429.

Schoedel A., Li M., Li D., O’Keeffe M., Yaghi O. M. Structures of metal–organic frameworks with rod secondary building units. Chemical Reviews. V. 116. N 19. P. 12466–12535.26. Barbov A., Shepelev M., Filippov D., Ulitin M. Effects of the nature and composition of the solvent on the thermody-namic characteristics of the individual forms of hydrogen adsorbed on the surface of porous nickel. Russian Journal of Physical Chemistry A. 2010. V. 84. N 9. P. 1605-1610.

Kiselev V.F., Kozlov S.N., Zoteev A.V. Fundamentals of solid state surface physics. Moscow: Publishing House of Moscow University. Faculty of Physics, Moscow State University, 1999. 284 p. (in Russian). 28. Tungler A.Thermal methods in the investigation of nickel catalysts. Journal of Thermal Analysis and Calorimetry. 2005. V. 79. P. 521–524.

Afineevsky A.V., Prozorov D.A., OsadchayaT.Yu., Rumyantsev R.N. Hydrogenation on heterogeneous cata-lysts. Kazan: Buk Publ., 2020. 476 p. (in Russian).

Barbov A.V., Gostikin V.P., Koifman O.I., Komarov A.A., Lefedova O.V., Merkin A.A., Nemtseva M.P., RomanenkoYu.E., Ulitin M.V., SharonovN.Yu. Theory and practice of liquid-phase hydrogenation of substituted compounds. Moscow: Krasand, 2016. 528 p. (in Russian). 31. Savitsky A., Zheludkevich M., Zaitsev A. Interaction of atomic hydrogen fluxes with the surface of solids. Energy ofthefuture. Saarbrucken: LapLambert, 2017. P. 46-160. 32. Temkin O.N. Chemistry of Molecular Hydrogen. Sov. Edu-cational Journal. 2000. V. 6. N 10. P. 31-36. (in Russian). 33. Startsev A.N. Hydrogen Sulfide as a Source of Hydrogen Production. Izvestiya of the Academy of Sciences, Chemical Series. 2017. N 8. P. 1378-1397. (in Russian).

Prozorov D.A., Barbov A.V., Filippov D.V., Merkin A.A. Physical Chemistry of Surface Phenomena: Hydrogen Ad-sorption on Palladium Catalysts. Journal of Physical Chem-istry. 2014. V. 88. N 6. P. 1026-1031. (in Russian). 35. Ryazanov M.A. States of hydrogen adsorbed on the surface of skeletal nickel. Journal of Physical Chemistry. 2012. V. 86. N 4. P. 748-748. (in Russian).

Barbov A.V., Prozorov D.A., Merkin A.A., Ulitin M.V. Heat of Hydrogen Sorption on Potted Palladium Catalysts. ChemChemTech [Izv. Vyssh.Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2013. V. 56. N 2. P. 49–53. (in Russian).

Ulitin M.V., Romanenko M.V., Lefedova O.V. Kinetics of Hydrogen Absorption by the Surface of Porous Nickel in an Aqueous Solution of Sodium Hydroxide. Journal of Physical Chemistry. 2012. V. 86. N 6. P. 1060-1065.

Smirnov D.V., Prozorov D.A., Afineevsky A.V. Investiga-tion of the possibility of predicting catalytic activity using IR spectrometry. Material xiv mizhnar.nauk.-tech. Confer-ence "Technology-2021", Severodonetsk, 2021. P. 72.

Startsev A.N., Zakharov I.I. Sulfide Hydrodesulfurization Cata-lysts: Structure of the Active Component and Catalytic Mechanism. Advances in Chemistry. 2003. V. 72. N 6. P. 579-601.

Smirnov D.V., Prozorov D.A., Afineevsky A.V., Meldin A.Yu. Identification of Individual Forms of Adsorbed Hy-drogen on the Surface of Catalysts Using the IR Spectros-copy Method. Tashkent. 2021. P. 470-471. (in Russian).

Smirnov D.V., Prozorov D.A., Afineevsky A.V. Express meth-od for determining individual forms of adsorbed hydrogen on transition metals and their-based catalysts. International Forum "Oil and Gas 2021". Moscow. 2020. P. 336-337. 42. Rodnikova M.N. Spatial grid of hydrogen bonds in liquids and solutions. Proceedings of the IV International Congress "Weak and ultra-weak fields and radiation in biology and medicine. St. Petersburg. 2006. P. 100-108. (in Russian).

Mukhtdinov E.A., Mukhtdinov A.A., Dyakonov G.S. Influence of low- and high-frequency shifts on the reactivity of inhibitor molecules. Bulletin of Kazan Technological University. 2006. N 1. P. 14-18. (in Russian44. Nesyn G.V., Shibaev V.P., Sunagatullin R.Z., Malkin A.Ya. Reducing the Hydrodynamic Resistance of Hydro-carbon Liquids: Theoretical and Practical Aspects. Science and Technologies of Pipeline Transport of Oil and Petrole-um Products. 2018. V. 8. N 3. P. 309-325. (in Russian).

Mashkovsky I.S., Tkachenko O.P., Baeva G.N., Stak- heev A.Yu. New Highly Selective Hydrogenation Catalysts Based on Bimetallic Acetate Complexes. Kinetics and Ca-talysis. 2009. V. 50. N 5. P. 798-805. (in Russian).

Krylov O.V. Heterogeneous Catalysis. Moscow: Akadem-kniga, 2004. 679 p. (in Russian).

Sokolsky D.V. Hydrogenation in Solutions. Alma-Ata: Nauka, 1979. 436 p. (in Russian).

Savelyev S.N., Savelyeva A.V., Fridland S.V. Research of the process of oxidation of hydrocarbons by air oxygen us-ing a heterogeneous catalyst and technological solution of its regeneration. Bulletin of Kazan Technological Universi-ty. 2016. V. 19. N 18. P. 182-185. (in Russian). 49. Lazarev M.Yu. Purification of exhaust gases from sulfur dioxide based on a catalyst from industrial waste // Ab-stract. Diss. Cand. Tech. Sci.: 03.02.08 Lazarev Mikhail Yurievich. Kazan, KNRTU. Kazan, 2012. 20 p.

Lazarev M.Yu., Sharafislamov F.Sh., Makhotkin I.A. Study of the Kinetics of the Catalytic Oxidation of SO2 to SO3 on a New and Regenerated SVD Catalyst. Bulletin of Kazan Techno-logical University. 2012. Vol. 15. N 5. P. 32−35.

Pakhare D., Spivey J. A review of dry (CO2) reforming of methane over noble metal catalysts. Chem. Soc. Rev. 2014. V. 43. P. 7813–7837.

Mortensen P., Dybkjaer I. Industrial scale experience on steam reforming of CO2-rich gas. Appl. Catal. A: Gen. 2015. V. 495. P. 141−151.

Hughes R. Deactivation of Catalysts. Moscow: Khimiya, 1989. 280 p. (in Russian).

Zavorin V.A., Fasman A.B., Mukhamedov R.Kh. Kinet-ics of thermodynamic desorption of hydrogen from nickel René catalysts. Kinetics and Catalysis. 1977. V. 18. N 4. P. 988-993. (in Russian).

Klyachko A.L. Heat of Adsorption on a Surface with Dis-crete Heterogeneity. Kinetics and Catalysis. 1978. V. 19. N 5. P. 1218-1223. (in Russian).

Ostrovsky N.M. Kinetics of Catalyst Deactivation: Math-ematical Models and Their Application. Moscow: Nauka, 2001. 335 p. (in Russian).

Coca J., Rosal R., Diez F., Sastre H.Decoloration of in-dene-coumarone resins by catalytic hydrogenation. J. Chem. Tech. Biotechnol. 1992. V. 53. P. 365–371. 58. Yurkina O.V., De Vecchi A.V., Kraev Yu.L. Mechanism of deactivation of palladium-containing hydrogenation cata-lysts in the presence of sulfur-containing substances. Petro-chemical Engineering. 2004. V. 44. N 3. P. 185-188. 59. Ilyin S.O., Petrukhina N.N., Kostyuk A.V., Dzhabarov E.G., Filatova M.P., Antonov S.V., Maksimov A.L. Hy-drogenation of Indene-Coumarone Resin on Palladium Cat-alysts for Use in Polymer Adhesives. Journal of Applied Chemistry. 2019. V. 92. N 8. P. 1051-1060. (in Russian).

Yablonsky G.S., Bykov V.I., Gorban A.N. Kinetic Models of Catalytic Reactions. Novosibirsk: Nauka, 1983. 254 p.

Kiperman S.L. Fundamentals of Chemical Kinetics in Heterogeneous Catalysis. Moscow: Khimiya, 1979. 350 p.

Panchenkov G.M., Lebedev V.P. Chemical kinetics and catalysis. Moscow: Chemistry, 1985. 552 p.

Dunleavy J. Sulfur as a catalyst poison. Platinum Metals Review. 2006. V. 50. N 2. P. 11.64. Balandin A.A. Catalysis. Theory and Research Methods. Moscow: Foreign Literature, 1955. 572 p. (in Russian).

Kirichenko O.G. Effect of ferroalloy gas purification rate on kinetics of red mud carbonization. Eastern-European Journal of Enterprise Technologies. 2013. V. 2. N 8. P. 37-41.

Yasumura J., Nakabayashi I. Study of Reney nickel cata-lysts by electron microprobe X-ray analyzer. Chem. Letters. 1972. V. 1. N 7. Р. 511-514. 67. Nesterov I.I. Alexandrov V.M. Ponomarev A.A. Zava-tsky M.D. Lobodenko E.I. Kobylinsky D.A. Kadyrov M.A. Experimental studies of radical reactions of hydrocar-bon raw materials conversion. Izvestiya vysshikh uchebnykh zavedeniy. Neft i gaz. 2019. N 4. P. 57-69. 68. Smolikov M.D., Shkurenok V.A., Yablokova S.S., Kiryanov D.I., Bely A.S. Patterns of Formation of the Ac-tive Surface of Tungstate-Containing Zirconium Dioxide as a Catalyst for the Isomerization of C7-Alkanes. Ros. Khim. Zh. 2018. V. 62. N 1-2. P. 73-88. (in Russian).

Smolikov M.D., Kazantsev K.V., Zatolokina E.V., Kiryanov, Paukshtis E.A., Bely A.S. Study of n-Hexane Isomerization on Pt/SO4/ZrO2/Al2O3 Catalysts: Influence of the Platinum State on Catalytic and Adsorption Properties. Kinetics and Catalysis. 2010. Vol. 51. N 4. P. 608–618.

Smolikov M.D., Goncharov V.B., Sadovskaya E.M., Kazantsev K.V., Zatolokina E.V., Kiryanov D.I., Paukshtis E.A., Balzhinimaev B.S., Bely A.S. Study of the Role of the Platinum State in Pt/SO4/ZrO2/Al2O3 Catalysts for the Isomerization of n-Hexane. Catalysis in Industry. 2013. N 6. P. 51–60. (in Russian). 71. Akchurin T.I., Baybulatova N.Z., Grabovsky S.A., Talipova R.R., Galkin E.G., Dokichev V.A. Hydrogena-tion of Alkenes in the Presence of Palladium Deposited on a Carbon-Silica Support. Kinetics and Catalysis. 2016. V. 57. N 5. P. 592-597. 72. Smirnov E.P., Prozorov D.A., Afineevsky A.V., Smirnov D.V., Filatova N.V. Hydrogen Adsorption as a Criterion for Selecting Substrates for Liquid-Phase Hydrogenation Cata-lysts. Advances in Chemistry and Chemical Technology. 2024. V. 38. P. 76-78.

Kunin A.V., Ilyin A.A., Morozov L.N., Smirnov N.N., Nikiforova T.E., Prozorov D.A., Rumyantsev R.N., Afineevskiy A.V., Borisova O.A., Grishin I.S., Veres K.A., Kurnikova A.A., Gabrin V.A., Gordina N.E. Cata-lysts and adsorbents for conversion of natural gas, fertilizers production, purification of technological liquids. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2023. V. 66. N 7. P. 132-150. DOI: 10.6060/ /ivkkt.20236607.6849j.

Published
2025-10-04
How to Cite
Смирнов, Д., Прозоров, Д., Афинеевский, А., & Никитин, К. (2025). CATALYSTS OF REACTIONS INVOLVING HYDROGEN: SYNTHESIS, FEATURES, ACTIVITY (REVIEW). Modern High Technologies. Regional Application, 83(3), 168-180. Retrieved from https://snt-isuct.ru/article/view/6773
Section
Инженерно-технически науки, машиностроение и технологии

Most read articles by the same author(s)