HYBRID MATERIALS OF COPPER PHTHALOCYANINE LIQUID-CRYSTALLINE COMPLEXES WITH CARBON NANOTUBES
Abstract
Hybrid materials were obtained by adsorbing molecules of tetra- and octasubstituted liq-uid-crystalline copper phthalocyanine complexes onto the surface of single-walled carbon nanotubes. The hybrid materials were characterized using electronic absorption spectroscopy, Raman spectrosco-py, and thermogravimetric analysis (TGA). The degree of SWCNT surface functionalization with phthalocyanine molecules was determined. It was demonstrated that increasing the number of substit-uents on the phthalocyanine macrocycle does not affect the degree of functionalization. The adsorp-tion-resistive sensor properties of the obtained hybrid materials toward low concentrations of gaseous ammonia were investigated. The sensor response magnitude of the hybrid materials was found to be 4 times higher than that of the pristine single-walled carbon nanotubes.
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Поступила в редакцию(Received) 10.04.2025
