ГИБРИДНЫЕ МАТЕРИАЛЫ ЖК-КОМПЛЕКСОВ ФТАЛОЦИАНИНА МЕДИ С УГЛЕРОДНЫМИ НАНОТРУБКАМИ
Аннотация
Получены гибридные материалы адсорбцией молекул тетра- и октазамещённых ЖК-комплексов фталоцианинов меди на поверхность одностенных углеродных нанотрубок (ОУНТ). Гибридные материалы были характеризованы методами электронной спектроско-пи поглощения, комбинационного рассеяния, термогравиметрией. Определена степень функ-ционализации поверхности ОУНТ молекулами фталоцианинов. Показано, что увеличение числа заместителей макроцикла фталоцианина не оказывает влияния на степень функцио-нализации. Исследованы адсорбционно-резистивные сенсорные свойства полученных гибрид-ных материалов по отношению к низким концентрациям газообразного аммиака. Показано, что величина сенсорного отклика гибридных материалов в 4 раза выше, чем и исходных од-ностенных углеродных нанотрубок.
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Поступила в редакцию(Received) 10.04.2025
